Survey of Plasticizers in Polyvinyl Chloride Toys
نویسندگان
چکیده
منابع مشابه
[Survey of plasticizers in polyvinyl chloride toys].
Plasticizers in 101 samples of polyvinyl chloride (PVC) toys on the Japanese market were surveyed. No phthalates were detected in designated toys, though bis(2-ethylhexyl)phthalate, diisononyl phthalate, diisobutyl phthalate, dibutyl phthalate, diisodecyl phthalate and benzyl butyl phthalate were detected in more than half of other toys. 2,2,4-Tributyl-1,3-pentanediol diisobutylate, o-acetyl tr...
متن کامل[Determination of organotin compounds in polyvinyl chloride toys].
Organotin compounds in polyvinyl chloride toys were determined by GC/MS after ethyl derivatization with sodium tetraethylborate. The samples were 12 balls, 12 soft toys, 10 food toys and 13 face masks for children. Monooctyltin, dioctyltin and trioctyltin compounds were found in all face masks at the levels of 74.8-917 micrograms/g. 474-3,960 micrograms/g and 1.0-213 micrograms/g, respectively....
متن کامل[Identification of unknown substances in polyvinyl chloride gloves containing non-phthalate plasticizers].
The use of polyvinyl chloride gloves containing di(2-ethylhexyl) phthalate for food contact applications is restricted. In their place, polyvinyl chloride gloves containing non-phthalate plasticizers (PVC-NP) have been introduced. They contained unknown substances, so they were studied by GC/MS, HR-MS and NMR. The chemical structures of the unknown substances were confirmed to be diethylene gly...
متن کاملAcyl Esters from Oxo-Derived Hydroxymethylstearates as Plasticizers for Polyvinyl Chloride
Hydroxymethylstearates were made by hydroformylation or oxo reaction of monoand polyunsaturated fats and esters with either rhodium-triphenylphosphine or cobalt carbonyl catalysts. Rhodium-oxo products were hydrogenated with nickel catalyst, whereas, cobalt-oxo products were heated directly under hydrogen pressure. Hydroxymethyl fatty alcohols also were prepared by a two-step copper-cmomite hyd...
متن کاملThermal Degradation of Polyvinyl Chloride
A survey is given of the recent advances in the study of and the present knowledge of the thermal degradation of polyvinyl chloride. The sites for initiation of the thermal degradation, the mechanism of the dehydrochiorination, the discolouration of PVC by heat and the influence of plasticizers on the rate of degradation are discussed.
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ژورنال
عنوان ژورنال: Food Hygiene and Safety Science (Shokuhin Eiseigaku Zasshi)
سال: 2012
ISSN: 0015-6426,1882-1006
DOI: 10.3358/shokueishi.53.19